• 文献标题:   CuO/graphene composite as anode materials for lithium-ion batteries
  • 文献类型:   Article
  • 作  者:   MAI YJ, WANG XL, XIANG JY, QIAO YQ, ZHANG D, GU CD, TU JP
  • 作者关键词:   graphene, cupric oxide, lithiumion battery, coulombic efficiency
  • 出版物名称:   ELECTROCHIMICA ACTA
  • ISSN:   0013-4686 EI 1873-3859
  • 通讯作者地址:   Zhejiang Univ
  • 被引频次:   291
  • DOI:   10.1016/j.electacta.2010.11.036
  • 出版年:   2011

▎ 摘  要

CuO/graphene composite is synthesized from CuO and graphene oxide sheets following reduced by hydrazine vapor. As the electrode material for lithium-ion batteries, CuO nanoparticles with sizes of about 30 nm homogeneously locate on graphene sheets, and act as spacers to effectively prevent the agglomeration of graphene sheets, keeping their high active surface. In turn, the graphene sheets with good electrical conductivity server as a conducting network for fast electron transfer between the active materials and charge collector, as well as buffered spaces to accommodate the volume expansion/contraction during discharge/charge process. The synergetic effect is beneficial for the electrochemical performances of CuO/graphene composite, such as improved initial coulombic efficiency (68.7%) and reversible capacity of 583.5 mAh g(-1) with 75.5% retention of the reversible capacity after 50 cycles. (C) 2010 Elsevier Ltd. All rights reserved.