• 文献标题:   Spontaneous Deposition of Prussian Blue on Reduced Graphene Oxide - Gold Nanoparticles Composites for the Fabrication of Electrochemical Biosensors
  • 文献类型:   Article, Proceedings Paper
  • 作  者:   BAI XY, SHIU KK
  • 作者关键词:   reduced graphene oxide, prussian blue, spontaneous deposition, composite material, biosensor
  • 出版物名称:   ELECTROANALYSIS
  • ISSN:   1040-0397 EI 1521-4109
  • 通讯作者地址:   Hong Kong Baptist Univ
  • 被引频次:   11
  • DOI:   10.1002/elan.201400358
  • 出版年:   2015

▎ 摘  要

A reduced graphene oxide-gold nanoparticles-Prussian blue (RGO-AuNPs-PB) composite was prepared by spontaneous deposition of PB on RGO-AuNPs surface. The GC/RGO-AuNPs-PB modified electrode offered good electrocatalytic activity toward the reduction of hydrogen peroxide, indicating the possible synergistic effects of the RGO-AuNPs-PB composite material. Direct electron transfer of glucose oxidase (GOD) can be realized after codeposition of GOD and chitosan (CHIT) coating on GC/RGO-AuNPs-PB electrode. The resulting GC/RGO-AuNPs-PB/GOD-CHIT biosensor exhibited an excellent amperometric response to glucose with a sensitivity of 84 mA M-1 cm(-2), and a linear range from 13 mu M to 2.0 mM at + 0.1 V vs. Ag vertical bar AgCl reference.