• 文献标题:   Controlled Growth of Multilayer, Few-Layer, and Single-Layer Graphene on Metal Substrates
  • 文献类型:   Article
  • 作  者:   YAO YG, LI Z, LIN ZY, MOON KS, AGAR J, WONG CP
  • 作者关键词:  
  • 出版物名称:   JOURNAL OF PHYSICAL CHEMISTRY C
  • ISSN:   1932-7447 EI 1932-7455
  • 通讯作者地址:   Georgia Inst Technol
  • 被引频次:   89
  • DOI:   10.1021/jp109002p
  • 出版年:   2011

▎ 摘  要

The effects of graphene growth parameters on the number of its layers were systematically studied and a new growth mechanism on Cu substrate was thus proposed. Through the investigation of the graphene growth parameters, including growth substrate types, carrier gases, types of carbon sources, growth temperature, growth time, and cooling rates, we found that graphene grows on Cu substrates via a surface-catalyzed process, followed by a templated growth. We can obtain either single layer graphene (SLG) or few-layer graphene (FLG) by suppressing the subsequent templated growth with a low concentration of carbon source gases and a high concentration of H-2. Our findings provide important guidance toward the synthesis of large-scale and high-quality FLGs and SLGs. This is expected to widen both the research and applications of graphene.