• 文献标题:   Graphene Growth Using a Solid Carbon Feedstock and Hydrogen
  • 文献类型:   Article
  • 作  者:   JI HX, HAO YF, REN YJ, CHARLTON M, LEE WH, WU QZ, LI HF, ZHU YW, WU YP, PINER R, RUOFF RS
  • 作者关键词:   graphene growth, amorphous carbon, hydrogen, hydrocarbon, mass spectroscopy
  • 出版物名称:   ACS NANO
  • ISSN:   1936-0851 EI 1936-086X
  • 通讯作者地址:   Univ Texas Austin
  • 被引频次:   69
  • DOI:   10.1021/nn202802x
  • 出版年:   2011

▎ 摘  要

Graphene has been grown on Cu at elevated temperatures with different carbon sources (gaseous hydrocarbons and solids such as polymers); however the detailed chemistry occurring at the Cu surface is not yet known. Here, we explored the possibility of obtaining graphene using amorphous-carbon thin films, without and with hydrogen gas added. Graphene is formed only In the presence of H-2(g), which strongly suggests that gaseous hydrocarbons and/or their Intermediates are what yield graphene on Cu through the reaction of H-2(g) and the amorphous carbon. The large area, uniform monolayer graphene obtained had electron and hole mobilities of 2520 and 2050 cm(2) V-1 s(-1), respectively.