• 文献标题:   Covalent and Noncovalent Functionalization and Solubilization of Graphene
  • 文献类型:   Article
  • 作  者:   SUBRAHMANYAM KS, GHOSH A, GOMATHI A, GOVINDARAJ A, RAO CNR
  • 作者关键词:   graphene, functionalization, solubilization, raman spectroscopy, transmission electron microscopy
  • 出版物名称:   NANOSCIENCE NANOTECHNOLOGY LETTERS
  • ISSN:   1941-4900
  • 通讯作者地址:   Jawaharlal Nehru Ctr Adv Sci Res
  • 被引频次:   63
  • DOI:   10.1166/nnl.2009.1014
  • 出版年:   2009

▎ 摘  要

While solubilization of graphene in nonpolar solvents can be accomplished through covalent functionalization, by involving the preparation of a long-chain alkylamide derivative, it is more easily accomplished by interaction with an organosilane or an organotin reagent such as hexadecyltrimethoxysilane and dibutyldimethoxytin. Noncovalent functionalization of graphene through pi-pi interaction by using 1-pyrenebutanoic acid succinimidyl ester gives stable dispersions in dimethylformamide. Interaction of graphene with surfactants produces stable aqueous dispersions, Igepal being effective even at low concentrations.