• 文献标题:   A One-Step Method for Preparation of Ru Nanoparticle Decorated on Three-Dimensional Graphene with High Catalytic Activity for Reduction of Nitroarenes
  • 文献类型:   Article, Early Access
  • 作  者:   DABIRI M, MIRAGHAEE S, NIKBAKHT R, BASHIRIBOD S
  • 作者关键词:   graphene, nanoparticle, ruthenium, reduction, nitroarene
  • 出版物名称:   JOURNAL OF CLUSTER SCIENCE
  • ISSN:   1040-7278 EI 1572-8862
  • 通讯作者地址:   Shahid Beheshti Univ
  • 被引频次:   0
  • DOI:   10.1007/s10876-020-01860-1 EA AUG 2020
  • 出版年:  

▎ 摘  要

Ruthenium nanoparticles on nitrogen and sulfur-doped three-dimensional graphene (Ru@NSG) nanohybrid were prepared via a one-pot hydrothermal method with graphene oxide (GO) and RuCl(3)as the raw materials and thiourea as a reducing-doping agent for the first time. The catalytic activity of nanohybrid was evaluated by the reduction of nitroarenes to the corresponding anilines. The effect of the weight ratio of Ru/GO was evaluated on catalytic activity. Moreover, in order to prove the role of the heteroatom substitution in graphene lattice, the Ru@NG and Ru@G hybrids were synthesized, and it was shown that the reaction yields would decrease in the presence of Ru@NG and Ru@G hybrids.