• 文献标题:   Selective and Sensitive Detection of Formaldehyde at Room Temperature by Tin Oxide Nanoparticles/Reduced Graphene Oxide Composite
  • 文献类型:   Article
  • 作  者:   KASHYAP A, CHAKRABORTY B, SIDDIQUI MS, TYAGI H, KALITA H
  • 作者关键词:   graphene, reduced graphene oxide rgo, rgosno2 composite, hydrothermal synthesi, formaldehyde sensor
  • 出版物名称:   ACS APPLIED NANO MATERIALS
  • ISSN:  
  • 通讯作者地址:  
  • 被引频次:   0
  • DOI:   10.1021/acsanm.3c01183 EA APR 2023
  • 出版年:   2023

▎ 摘  要

A highly selective formaldehyde (HCHO) gas sensor using a tin oxide nanoparticles-reduced graphene oxide (rGO-SnO2) composite has been fabricated and investigated for room-temperature sensing. The rGO-SnO2 composite is synthe-sized by cost-effective wet chemical method. The fabricated sensor exhibits remarkable sensing performance, including a higher response, a low detection limit of approximate to 33 ppb (theoretical), good selectivity, and long-term stability. Furthermore, the effects of humidity level and calcination temperature have also been investigated. The response and recovery times for 10 ppm HCHO vapor are found to be 35 and 10 s, respectively. The promising results in the lab-scale HCHO detection with pre-treated fish opens up avenues for the non-invasive detection of HCHO in food adulteration. The density functional theory study is in good agreement with the experimental results. The electronic charge density differences of the rGO-SnO2 composite in the proximity of HCHO show significant variation. In addition, the sensing mechanism of the rGO-SnO2 composite toward HCHO has also been discussed.