• 文献标题:   Catalytic performance of Pt nanoparticles on reduced graphene oxide for methanol electro-oxidation
  • 文献类型:   Article
  • 作  者:   LI YJ, GAO W, CI LJ, WANG CM, AJAYAN PM
  • 作者关键词:  
  • 出版物名称:   CARBON
  • ISSN:   0008-6223 EI 1873-3891
  • 通讯作者地址:   Lanzhou Univ
  • 被引频次:   705
  • DOI:   10.1016/j.carbon.2009.11.034
  • 出版年:   2010

▎ 摘  要

We have investigated a simple approach for the deposition of platinum (Pt) nanoparticles onto surfaces of graphite oxide (GO) nanosheets with particle size in the range of 1-5 nm by ethylene glycol reduction. During Pt deposition, a majority of oxygenated functional groups on GO was removed, which resulted in a Pt/chemically converted graphene (Pt/CCG) hybrid. The electrochemically active surface areas of Pt/CCG and a comparative sample of Pt/multi-walled carbon nanotubes (Pt/MWCNT) are 36.27 and 33.43 m(2)/g, respectively. The Pt/CCG hybrid shows better tolerance to CO for electro-oxidation of methanol compared to the Pt/MWCNT catalyst. Our study demonstrates that CCG can be an alternative two-dimensional support for Pt in direct methanol fuel cells. (C) 2009 Elsevier Ltd. All rights reserved.