• 文献标题:   Bilayer graphene synthesis by plasma treatment of copper foils without using a carbon-containing gas
  • 文献类型:   Article
  • 作  者:   KATO R, TSUGAWA K, OKIGAWA Y, ISHIHARA M, YAMADA T, HASEGAWA M
  • 作者关键词:  
  • 出版物名称:   CARBON
  • ISSN:   0008-6223 EI 1873-3891
  • 通讯作者地址:   Natl Inst Adv Ind Sci Technol
  • 被引频次:   24
  • DOI:   10.1016/j.carbon.2014.05.087
  • 出版年:   2014

▎ 摘  要

Bilayer graphene has been synthesized by using hydrogen plasma treatment of copper foils for 30 s at the temperature of 850 degrees C together with joule-heating treatment of the foils without using a carbon-containing gas such as methane in order to suppress the nucleation density of graphene. The effect of plasma provides active species of carbon atoms on copper substrate and a selective bilayer graphene formation of AB-stacking in a very short time. Carbon to be precipitated is delivered from the copper foil and/or the environment in the reaction chamber. The domain size of synthesized graphene, the controllability of a few layers and the electrical conductivity have been significantly improved compared with plasma chemical vapor deposition (CVD) using carbon-containing gas. The sheet resistance of bilayer graphene exhibits 951 Omega in average. The carrier mobility shows 1000 cm(2)/V s in maximum at room temperature. The sheet resistance of 130 +/- 26 Omega has been attained after the doping by gold chloride solution. (C) 2014 Elsevier Ltd. All rights reserved.