• 文献标题:   Nanographene-Constructed Carbon Nanofibers Grown on Graphene Sheets by Chemical Vapor Deposition: High-Performance Anode Materials for Lithium Ion Batteries
  • 文献类型:   Article
  • 作  者:   FAN ZJ, YAN J, WEI T, NING GQ, ZHI LJ, LIU JC, CAO DX, WANG GL, WEI F
  • 作者关键词:   graphene nanosheet, carbon nanofiber, lithium ion battery
  • 出版物名称:   ACS NANO
  • ISSN:   1936-0851
  • 通讯作者地址:   Harbin Engn Univ
  • 被引频次:   197
  • DOI:   10.1021/nn200195k
  • 出版年:   2011

▎ 摘  要

We report on the fabrication of 3D carbonaceous material composed of 1D carbon nanofibers (CNF) grown on 2D graphene sheets (GNS) via a CVD approach in a fluidized bed reactor. Nanographene-constructed carbon nanofibers contain many cavities, open tips, and graphene platelets with edges exposed, providing more extra space for Li(+) storage. More interestingly, nanochannels consisting of graphene platelets arrange almost perpendicularly to the fiber axis, which is favorable for lithium Ion diffusion from different orientation In addition, 3D interconnected architectures facilitate the collection and transport of electrons during the cycling process. As a result, the CNF/GNS hybrid material shows high reversible capacity (667 mAh/g), high-rate performance, and cycling,stability, which is superior to those of purE graphene, natural graphite, and carbon nanotubes. The simple,CVD approach offers a new pathway for large-scale production of novel hybrid carbon materials for energy storage.