• 文献标题:   Graphene oxide/Cu(OH)(2) composites as efficient multifunctional hosts for lithium-sulfur batteries
  • 文献类型:   Article
  • 作  者:   SHI ZY, DU R, YU CB, RAO WH, XU CY, WANG JL
  • 作者关键词:   graphene oxide, cu oh 2, lithiumsulfur batterie, cathode
  • 出版物名称:   JOURNAL OF ALLOYS COMPOUNDS
  • ISSN:   0925-8388 EI 1873-4669
  • 通讯作者地址:  
  • 被引频次:   1
  • DOI:   10.1016/j.jallcom.2022.166642 EA AUG 2022
  • 出版年:   2022

▎ 摘  要

Lithium-sulfur batteries are advanced energy storage system with high theoretical specific capacity and low cost but suffer from poor cyclic performance. To overcome the shortcomings, this study synthesized graphene oxide (GO)/Cu(OH)(2) composites using the modified Hummers method and electrostatic self-assembly process. The sulfur was anchored in the GO/Cu(OH)(2) composites using the melting method. The oxygen-containing function groups of GO are helpful for achieving good ion/electron accessibility, and the interlayers of GO have many active sites for polysulfide conversion. The polar hydrophilic hydroxyl group of Cu(OH)(2) particles have strong chemisorption for polysulfides during the electrochemical process. Therefore, the synergistic effect of GO and Cu(OH)(2) in the composites as sulfur hosts can inhibit the dissolution and shuttling of polysulfides. The lithium-sulfur batteries with GO/Cu(OH)(2) composites as hosts have high capacity of 1427 mAh g(-1) at 0.1 C, 1222 mAh g(-1) at 0.5 C, and excellent cyclic performance for 250 cycles with a retained capacity of 929 mAh g(-1) (0.5 C). (C) 2022 Elsevier B.V. All rights reserved.