1. 平台首页
  2. 国际论文信息
  • 文献标题:   Electrografting of amino-TEMPO on graphene oxide and electrochemically reduced graphene oxide for electrocatalytic applications
  • 文献类型:   Article
  • 作　　者:   YUAN BQ, XU CY, ZHANG DJ, ZHANG RC, SU HM, GUAN P, NIE JJ, FERNANDEZ C
  • 作者关键词:   4aminotempo, nitroxide radical, electrochemically reduced graphene oxide, reduced glutathione, hydrogen peroxide
  • 出版物名称:   ELECTROCHEMISTRY COMMUNICATIONS
  • ISSN:   1388-2481 EI 1873-1902
  • 通讯作者地址:   Anyang Normal Univ
  • 被引频次:   7
  • DOI:   10.1016/j.elecom.2017.05.016
  • 出版年:   2017

▎ 摘　　要

4-Amino-2,2,6,6-tetramethyl-1-piperridine N-oxyl (4-amino-TEMPO), an electroactive nitroxide radical, was attached to the surface of graphene oxide (GO) and electrochemically reduced graphene oxide (ERGO) modified glassy carbon electrode by a simple, rapid and green electrografting method. The electroactive interfaces were analyzed by X-ray photoelectron spectroscopy (XPS) and cyclic voltammetry (CV). The calculated surface coverage for 4-amino-TEMPO is up to 1.55 x10(-9) mol.cm(-2). The modified electroactive interface exhibited excellent electrocatalytic activity towards the electro-oxidation of reduced glutathione (GSH) and hydrogen peroxide (H2O2).