• 文献标题:   Dual Stimuli-Responsive Smart Fluid of Graphene Oxide-Coated Iron Oxide/Silica Core/Shell Nanoparticles
  • 文献类型:   Article
  • 作  者:   LEE S, NOH J, HONG S, KIM YK, JANG J
  • 作者关键词:  
  • 出版物名称:   CHEMISTRY OF MATERIALS
  • ISSN:   0897-4756 EI 1520-5002
  • 通讯作者地址:   Seoul Natl Univ
  • 被引频次:   27
  • DOI:   10.1021/acs.chemmater.5b04936
  • 出版年:   2016

▎ 摘  要

The graphene oxide-coated iron oxide/silica core/shell nanoparticles (Fe3O4/SiO2/GO NPs) are successfully fabricated and adopted as the dual stimuli-responsive smart fluid. The Fe3O4/SiO2/GO NPs exhibit both electrorheological (ER) and magnetorheological (MR) characteristics, attributed to the SiO2/GO layer in the shell part and Fe3O4 in the core part, respectively. Particularly, the ER efficiency of the Fe3O4/SiO2/GO NPs-based ER fluid is ca. 191 at the applied electric field of 3 kV mm(-1). Moreover, the MR performance of the Fe3O4/SiO2/GO NPs-based MR fluid is significantly enhanced up to 135-fold at the applied magnetic field of 1 T compared to the zero-field stress. Furthermore, it is remarkable that the Fe3O4/SiO2/GO NPs represent high colloidal stability and outstanding antisettling property because of the electrostatic repulsion between oxygen functional groups on GO nanosheets and the relatively low density compared with other magnetic particles. Dual stimuli-responsive characteristics in addition to the excellent antisedimentation property of the Fe3O4/SiO2/GO NPs-based smart fluid would provide a feasible candidate for practical applications.