• 文献标题:   Wettability modification of graphene oxide by removal of carboxyl functional groups using non-thermal effects of microwave
  • 文献类型:   Article
  • 作  者:   RASULI R, MOKARIAN Z, KARIMI R, SHABANZADEH H, ABEDINI Y
  • 作者关键词:   graphene oxide, microwave, wettability
  • 出版物名称:   THIN SOLID FILMS
  • ISSN:   0040-6090
  • 通讯作者地址:   Univ Zanjan
  • 被引频次:   16
  • DOI:   10.1016/j.tsf.2015.06.002
  • 出版年:   2015

▎ 摘  要

We study the non-thermal effects of microwave on the wettability of graphene oxide. It is shown that removal of carboxyl compound by using the non-thermal microwave effects decrease the wettability of graphene oxide. X-ray photoelectron spectroscopy (C1s and O1s peaks) and Fourier transform infrared spectroscopy show that carboxyl compound decreases dramatically due to microwave irradiation while other functional groups were gradually reduced. Consequently, after 20 min microwave irradiation, carboxyl functional groups are removed. Wettability tests of carboxyl-reduced graphene oxide show that water uptake capability decreases to half and contact angle of water droplets increases from similar to 29.7 degrees to similar to 69.9 degrees. (C) 2015 Elsevier B.V. All rights reserved.