• 文献标题:   Design and synthesis of an organic (naphthoquinone) and inorganic (RuO2) hybrid graphene hydrogel composite for asymmetric supercapacitors
  • 文献类型:   Article
  • 作  者:   ZHANG ZY, GUO BS, WANG XT, LI ZM, YANG YY, HU ZA
  • 作者关键词:  
  • 出版物名称:   NEW JOURNAL OF CHEMISTRY
  • ISSN:   1144-0546 EI 1369-9261
  • 通讯作者地址:   Northwest Normal Univ
  • 被引频次:   3
  • DOI:   10.1039/c8nj01908h
  • 出版年:   2018

▎ 摘  要

The naphthoquinone and RuO2 hybrid graphene hydrogel (NQ-RuO2/SGH) composite, which can be a suitable positive electrode material of an asymmetric supercapacitor, is prepared via a two-step process. The RuO2/graphene hydrogel composite (RuO2/SGH) is first synthesized through a simple hydrothermal method by using oxidized graphite (GO) and RuCl3 as raw materials, and then, 1,4-naphthoquinone (NQ) molecules are adsorbed on the exposed graphene hydrogel surface of the RuO2/SGH composite via a - stacking interaction. The electrochemical tests show that the NQ-RuO2/SGH composite delivers a high specific capacitance (450.8 F g(-1)) even at a low RuO2 loading mass (14.6%), meanwhile, an asymmetric supercapacitor (ASC) is constructed by using NQ-RuO2/SGH as the positive electrode and a nitrogen-doped porous carbon material (MNC) as the negative electrode. The electrochemical measurements prove that the energy density of the ASC can reach up to 16.3 W h kg(-1) in a 1 M H2SO4 electrolyte.