• 文献标题:   A Novel Method for Bisphenol A Analysis in Dairy Products Using Graphene as an Adsorbent for Solid Phase Extraction Followed by Ion Chromatography
  • 文献类型:   Article
  • 作  者:   WANG ZH, CUI H, XIA JF, HAN Q, LV NN, GAO JG, GUO XM, ZHANG FF, MA JM, SU GK
  • 作者关键词:   ion chromatography, bisphenol a, constant potential detection, solid phase extraction, graphene, dairy product
  • 出版物名称:   FOOD ANALYTICAL METHODS
  • ISSN:   1936-9751 EI 1936-976X
  • 通讯作者地址:   Qingdao Univ
  • 被引频次:   15
  • DOI:   10.1007/s12161-013-9567-y
  • 出版年:   2013

▎ 摘  要

A novel and reliable ion chromatography (IC) method using graphene (G) as a solid phase extraction (SPE) adsorbent for the rapid analysis of bisphenol A (BPA) in dairy products was developed. The performances of graphene (G) and commercial C18 for BPA extraction from dairy samples were evaluated; results showed that G had higher adsorption efficiency. IC coupled with an electrochemical detector (ED) is eco-friendly, labor and time saving compared to liquid chromatography mass spectrometry (LC-MS) and gas chromatography mass spectrometry (GC-MS). The effects of the experimental parameters of the IC-ED system were assessed, and the parameters were optimized to provide maximum sensitivity. The linear range is 5-20,000 ng mL(-1) with an R value of 0.999. The limit of the detection is 0.8 ng mL(-1) for a 25-mu L injection loop. The mean relative recoveries ranged between 83.3 % and 104.6 %, the corresponding inter-day precision was below 5.3 % for 20, 200, 2,000, and 15,000 ng mL(-1). This method was successfully employed to analyze BPA in dairy samples.