• 文献标题:   Sulfonated graphene oxide from petrochemical waste oil for efficient conversion of fructose into levulinic acid
  • 文献类型:   Article
  • 作  者:   LAWAGON CP, FAUNGNAWAKIJ K, SRINIVES S, THONGRATKAEW S, CHAIPOJJANA K, SMUTHKOCHORN A, SRISRATTHA P, CHARINPANITKUL T
  • 作者关键词:   sulfonated graphene oxide, catalyst, petrochemical waste oil, fructose, levulinic acid
  • 出版物名称:   CATALYSIS TODAY
  • ISSN:   0920-5861 EI 1873-4308
  • 通讯作者地址:  
  • 被引频次:   7
  • DOI:   10.1016/j.cattod.2020.02.036 EA JUN 2021
  • 出版年:   2021

▎ 摘  要

Handling of petrochemical waste oil (PWO) is costly, tedious, and risky to human health and environment. Hence, upcycling of PWO for biomass conversion to platform chemicals would be very advantageous. Herein, a highly porous sheet-like structure of sulfonated graphene oxide (sGO) catalyst was synthesized from PWO. The synthesized sGO possessed high surface area (246.2 m(2) g(1)) due to its mesoporosity and high content of sulfonic groups (2.4 mmol g(-1)) grafted onto its surface. As its application, the synthesized sGO was employed to convert fructose to levulinic acid (LA) within deionized water. The high yield (61.2 mol %) of LA was obtained under a condition of 160 degrees C, 1 h, and 6 g g(-1) fructose to sGO weight ratio. It can be reused several times (5 runs) with no severe degradation of catalytic activity. Therefore, the sGO derived from petrochemical waste oil would be considered as an environmentally benign catalyst for producing platform chemicals, i.e. LA from fructose and other biomass derivatives.