• 文献标题:   Comparison of electronic structure and template function of single-layer graphene and a hexagonal boron nitride nanomesh on Ru(0001)
  • 文献类型:   Article
  • 作  者:   BRUGGER T, GUNTHER S, WANG B, DIL JH, BOCQUET ML, OSTERWALDER J, WINTTERLIN J, GREBER T
  • 作者关键词:  
  • 出版物名称:   PHYSICAL REVIEW B
  • ISSN:   1098-0121
  • 通讯作者地址:   Univ Zurich
  • 被引频次:   144
  • DOI:   10.1103/PhysRevB.79.045407
  • 出版年:   2009

▎ 摘  要

The structure of a single-layer graphene on Ru(0001) is compared with that of a single-layer hexagonal boron nitride nanomesh on Ru(0001). Both are corrugated sp(2) hybridized networks and display a pi band gap at the (K) over bar point of their 1 x 1 Brillouin zone. In contrast to h-BN/Ru(0001), g/Ru(0001) has a distinct Fermi surface. Together with the band structure measurements this indicates that 0.1e per 1 x 1 unit cell are transferred from the Ru substrate to the graphene. Photoemission from adsorbed xenon on g/Ru(0001) identifies two Xe 5p(1/2) lines, separated by 240 meV, which reveals a corrugated electrostatic potential energy surface like on h-BN/Rh(111). These two Xe species are related to the topography of the template and have different desorption energies.