• 文献标题:   Pyronine B/Graphene Copolymer Modified Carbon Molecular Wire Electrode for Electrochemical Detection of Quercetin
  • 文献类型:   Article
  • 作  者:   ZHANG XP, SHAO B, YAN LJ, LU YP, ZHAO MX, HE XL, LI XR, SUN W
  • 作者关键词:   pyronine b, graphene, electrochemistry, quercetin
  • 出版物名称:   INTERNATIONAL JOURNAL OF ELECTROCHEMICAL SCIENCE
  • ISSN:   1452-3981
  • 通讯作者地址:  
  • 被引频次:   2
  • DOI:   10.20964/2021.01.66
  • 出版年:   2021

▎ 摘  要

By using cyclic voltammetric method a pyronine B (PB) and graphene (GR) copolymer was electrochemical formed on carbon molecular wire electrode (CMWE) to get the working electrode (named as PB-GR/CMWE). The synergistic functions of PB and GR resulted in the excellent electrochemical performances with higher conductivity and lower interfacial resistances. Voltammetric behaviors of quercetin on PB-GR/CMWE were investigated by cyclic voltammetry, which gave a pair of well-defined redox response in pH 5.0 phosphate buffer solution. Under the selected conditions, the oxidation peak currents were in linear to quercetin concentration from 0.2 similar to 80.0 mu mol L-1 with the detection limit as 6.37x 10(-8) mol L-1 (3 sigma). The fabricated PB-GR/CMWE was further used to detect quercetin in compound ginkgo leaf tablets with satisfactory results.