• 文献标题:   Graphene nanoribbons as a novel support material for high performance fuel cell electrocatalysts
  • 文献类型:   Article
  • 作  者:   WANG CN, LI H, ZHAO JH, ZHU Y, YUAN WZ, ZHANG YM
  • 作者关键词:   graphene nanoribbon, nanohybrid catalyst, electrochemical stability, direct methanol fuel cell
  • 出版物名称:   INTERNATIONAL JOURNAL OF HYDROGEN ENERGY
  • ISSN:   0360-3199 EI 1879-3487
  • 通讯作者地址:   Shanghai Jiao Tong Univ
  • 被引频次:   28
  • DOI:   10.1016/j.ijhydene.2013.07.111
  • 出版年:   2013

▎ 摘  要

Graphene nanoribbons (GNRs) were first used as a novel support material for Pt nano-particles (NPs) based catalyst for methanol electro-oxidation. Upon oxidation and cutting of multiwall carbon nanotubes (MWCNTs), highly dispersive graphene oxide nanoribbons (GONRs) were obtained, on which metal ions such as PtCl62- can be homogenously deposited. The hybrid catalyst of GNRs supported Pt NPs (Pt/GNR) was further prepared through facile in-situ chemical co-reduction, with a homogeneous distribution of Pt NPs (2 -3 nm) on the nanoribbons. Compared to Pt/MWCNT and commercial Pt/XC72R catalysts, Pt/GNR hybrids show much larger electrochemically active surface area, higher electrochemical stability, and better CO tolerance towards electro-oxidation of methanol. Therefore, GNR is a promising alternative two-dimensional support material for electrocatalysts in direct methanol fuel cells. Copyright (C) 2013, Hydrogen Energy Publications, LLC. Published by Elsevier Ltd. All rights reserved.