• 文献标题:   Modeling mercury (II) removal at ultra-low levels from aqueous solution using graphene oxide functionalized with magnetic nanoparticles: optimization, kinetics, and isotherm studies
  • 文献类型:   Article
  • 作  者:   KHAZAEI M, NASSERI S, GANJALI MR, KHOOBI M, NABIZADEH R, MAHVI AH, GHOLIBEGLOO E, NAZMARA S
  • 作者关键词:   graphene oxide, adsorption, mercury ii, response surface methodology, central composite design, model
  • 出版物名称:   DESALINATION WATER TREATMENT
  • ISSN:   1944-3994 EI 1944-3986
  • 通讯作者地址:   Univ Tehran Med Sci
  • 被引频次:   9
  • DOI:   10.5004/dwt.2017.21066
  • 出版年:   2017

▎ 摘  要

Magnetic graphene oxide (Fe3O4@SiO2-GO) nanocomposite was fabricated through a facile process and its application was found to be an excellent adsorbent for capturing low concentrations of mercury (II) from water. The effects of four independent factors, including nanocomposite dosage, contact time, pH, and initial mercury ion concentration on the mercury (II) removal were studied, and the process was optimized using response surface methodology (RSM). The optimum values of the variables adsorbent dosage, contact time, pH, and mercury (II) initial concentration were found to be 23 mg L-1, 21 min, 5.5, and 550 ppb, respectively. The adsorbent equilibrium capacity was 328.3 mg g(-1) after 21 min. By using goodness-of-fit measures (GoFMs), the Sips isotherm was found to provide a good fit with the adsorption data (K-S = 0.388 L mg(-1), n(S) = 0.44, q(m) = 569.3 mg g(-1), and R-2 = 0.989). The mean free energy E-ads was 11.901 kJ/mol, confirmed chemisorption mechanisms. The kinetic study determined good compliance of experimental data with the double exponential kinetic model (R-2 = 0.997).