• 文献标题:   Graphene on Ru(0001) Moire Corrugation Studied by Scanning Tunneling Microscopy on Au/Graphene/Ru(0001) Heterostructures
  • 文献类型:   Article
  • 作  者:   CORTES R, ACHARYA DP, CIOBANU CV, SUTTER E, SUTTER P
  • 作者关键词:  
  • 出版物名称:   JOURNAL OF PHYSICAL CHEMISTRY C
  • ISSN:   1932-7447 EI 1932-7455
  • 通讯作者地址:   Brookhaven Natl Lab
  • 被引频次:   10
  • DOI:   10.1021/jp406415h
  • 出版年:   2013

▎ 摘  要

Two-dimensional Au islands of different thicknesses grown on graphene/Ru(0001) were used to study the corrugation of the moire structure of graphene/Ru(0001) and discriminate between its mainly structural or electronic character. A comparison of the apparent corrugation measured by scanning tunneling microscopy (STM) for different Au thicknesses with results of elasticity theory equations applied to a gold film over a corrugated substrate shows that the corrugation observed for the graphene/Ru(0001) moire is of structural nature rather than electronic. STM showed a large value for the corrugation of the first Au monolayer on graphene/Ru(0001), similar to 1.7 angstrom; using density functional theory calculations, we explain this large corrugation of the Au monolayer as the result of a strong (weak) binding of the Au layer at the valley (hill) regions of the graphene/Ru(0001) moire structure and infer an actual corrugation of the graphene/Ru(0001) moire structure of similar to 1.2 angstrom from the measured corrugation of the Au monolayer.