▎ 摘　　要

A selective, efficient and benign oxidative coupling of benzylamine under microwave irradiation was achieved at mild reaction conditions in the absence of oxidant using graphene oxide as catalyst. Reaction conditions seem to point to the favoured formation of an imine intermediate which subsequently reacts with benzylamine to provide high selectivities at almost quantitative conversion of starting material to the oxidative coupling product N-benzylidine-1-phenylmethanamine. A plausible reaction mechanism is proposed. (C) 2015 Elsevier B.V. All rights reserved.