• 文献标题:   Preparation and electrochemical performance of a CuO/graphene composite
  • 文献类型:   Article
  • 作  者:   DING X, HUANG ZH, SHEN WC, KANG FY
  • 作者关键词:   graphene oxide, graphene, cuo, liion battery
  • 出版物名称:   NEW CARBON MATERIALS
  • ISSN:   1007-8827
  • 通讯作者地址:   Tsinghua Univ
  • 被引频次:   4
  • DOI:  
  • 出版年:   2013

▎ 摘  要

Graphene oxide was synthesized from expanded graphite powder by a simple one-step oxidation method. A CuO/graphene composite was then obtained using a hydrothermal method. The samples were characterized using AFM, XRD, SEM, TEM and electrochemical measurements. Results glow that CuO acts as a spacer to prevent the agglomeration of graphene sheets. The graphene formed a 3D conducting network for fast electron transfer, as well as space to accommodate the volume expansion/contraction of CuO during the discharge/charge process. The CuO/graphene composite exhibits enhanced electrochemical performance compared with pure CuO and graphene, such as improved initial coulombic efficiency (69.9%) and a reversible capacity of 748.3 mAh/g with 81.3% retention after 50 cycles.