• 文献标题:   Performance Comparison of Reduced Graphene Oxide (rGO)-polyaniline (PANI) Supercapacitors with LiCl, Li2SO4, and H2SO4 Electrolytes
  • 文献类型:   Article
  • 作  者:   CHO WH, CHENG IC, CHEN JZ
  • 作者关键词:  
  • 出版物名称:   JOURNAL OF THE ELECTROCHEMICAL SOCIETY
  • ISSN:   0013-4651 EI 1945-7111
  • 通讯作者地址:  
  • 被引频次:   2
  • DOI:   10.1149/1945-7111/acb38b
  • 出版年:   2023

▎ 摘  要

Reduced graphene oxide (rGO)-polyaniline (PANI) supercapacitors (SCs) are tested with 1 M LiCl, Li2SO4, and H2SO4 electrolytes. The SC performance is evaluated by electrical impedance spectroscopy, cyclic voltammetry (CV), and galvanostatic charging/discharging measurements. Electrochemical experiments indicate that rGO-PANI SCs with lithium salt electrolytes show a large pseudocapacitance (PC) effect whereas that with H2SO4 electrolyte shows a large electrical double-layer capacitance (EDLC) effect. The rGO-PANI SC with H2SO4 electrolyte has the largest areal capacitance of 48.83 mF/cm(2), whereas those with LiCl and Li2SO4 electrolytes have the areal capacitances of 31.69 mF/cm(2) and 22.35 mF/cm(2), respectively. After a 10,000-cycle CV stability test, the rGO-PANI SC with Li2SO4 electrolyte shows some ion embedding, resulting in better cycling stability than those of SCs with LiCl and H2SO4 electrolytes.