• 文献标题:   Nanocrystalline tin disulfide coating of reduced graphene oxide produced by the peroxostannate deposition route for sodium ion battery anodes
  • 文献类型:   Article
  • 作  者:   PRIKHODCHENKO PV, YU DYW, BATABYAL SK, UVAROV V, GUN J, SLADKEVICH S, MIKHAYLOV AA, MEDVEDEV AG, LEV O
  • 作者关键词:  
  • 出版物名称:   JOURNAL OF MATERIALS CHEMISTRY A
  • ISSN:   2050-7488 EI 2050-7496
  • 通讯作者地址:   City Univ Hong Kong
  • 被引频次:   81
  • DOI:   10.1039/c3ta15248k
  • 出版年:   2014

▎ 摘  要

A highly stable sodium ion battery anode was prepared by deposition of hydroperoxostannate on graphene oxide from hydrogen-peroxide-rich solution followed by sulfidization and 300 degrees C heat treatment. The material was characterized by electron microscopy, powder X-ray diffraction and X-ray photoelectron spectroscopy which showed that the active material is mostly rhombohedral SnS2 whose (001) planes were preferentially oriented in parallel to the graphene oxide sheets. The material exhibited >610 mA h g(-1) charge capacity at 50 mA g(-1) (with >99.6% charging efficiency) between 0 and 2 V vs. Na/Na+ electrode, high cycling stability for over 150 cycles and very good rate performance, >320 mA h g(-1) at 2000 mA g(-1).