• 文献标题:   Micro-/Mesoporous Zinc-Manganese Oxide/Graphene Hybrids with High Specific Surface Area: A High-Capacity, Superior-Rate, and Ultralong-Life Anode for Lithium Storage
  • 文献类型:   Article
  • 作  者:   YAO W, ZHAO MQ, DAI Y, TANG JL, XU JG
  • 作者关键词:   energy storage, graphene, lithiumion batterie, manganese, zinc
  • 出版物名称:   CHEMELECTROCHEM
  • ISSN:   2196-0216
  • 通讯作者地址:   Yancheng Inst Technol
  • 被引频次:   5
  • DOI:   10.1002/celc.201600564
  • 出版年:   2017

▎ 摘  要

Hierarchical porous mixed metal oxide/graphene two-dimensional nanostructures, providing an extra active position for lithium storage, represent a hopeful platform for next-generation anode materials. Herein, we report a facile approach to synthesize micro-/mesoporous zinc-manganese oxide/graphene (Zn-Mn-O/G) hybrids with a specific surface area of 227.6 m(2)g(-1) in a water/ethanol mixed solvent. Owing to the micro-/mesoporous structure, large specific area, and strongly coupled effects between Zn-Mn-O and the graphene sheets, the hybrids deliver a high capacity of 1216mAhg(-1) at a current density of 500 mAg(-1) after 100cycles, a superior rate performance of 558mAhg(-1) at 8000 mAg(-1), as well as ultralong cycle life up to 900 cycles. In addition, if performed in the temperature range of 5 to 45 degrees C, the Zn-Mn-O/G anode demonstrates specific capacities between 748 and 1245 mAhg(-1) after 100 cycles.