• 文献标题:   A Lithium-Ion Battery using a 3D-Array Nanostructured Graphene-Sulfur Cathode and a Silicon Oxide-Based Anode
  • 文献类型:   Article
  • 作  者:   BENITEZ A, DI LECCE D, ELIA GA, CABALLERO A, MORALES J, HASSOUN J
  • 作者关键词:   graphene, lithiumion batterie, microwave chemistry, silicon, sulfur
  • 出版物名称:   CHEMSUSCHEM
  • ISSN:   1864-5631 EI 1864-564X
  • 通讯作者地址:   Univ Cordoba
  • 被引频次:   17
  • DOI:   10.1002/cssc.201800242
  • 出版年:   2018

▎ 摘  要

An efficient lithium-ion battery was assembled by using an enhanced sulfur-based cathode and a silicon oxide-based anode and proposed as an innovative energy-storage system. The sulfur-carbon composite, which exploits graphene carbon with a 3D array (3DG-S), was synthesized by a reduction step through a microwave-assisted solvothermal technique and was fully characterized in terms of structure and morphology, thereby revealing suitable features for lithium-cell application. Electrochemical tests of the 3DG-S electrode in a lithium half-cell indicated a capacity ranging from 1200 to 1000mAhg(-1) at currents of C/10 and 1C, respectively. Remarkably, the Li-alloyed anode, namely, LiySiOx-C prepared by the sol-gel method and lithiated by surface treatment, showed suitable performance in a lithium half-cell by using an electrolyte designed for lithium-sulfur batteries. The LiySiOx-C/3DG-S battery was found to exhibit very promising properties with a capacity of approximately 460mAhg(S)(-1) delivered at an average voltage of approximately 1.5V over 200cycles, suggesting that the characterized materials would be suitable candidates for low-cost and high-energy-storage applications.