• 文献标题:   Improved Lithium Storage Properties of the Reduced Graphene Oxide/Graphite Composites Based on Functional Groups Control Synthesis
  • 文献类型:   Article
  • 作  者:   JIAO DH, XIE ZW, WAN Q, WEI ZK, YAN XX, BUTT FK, QU MZ
  • 作者关键词:   lithium storage, graphene oxide, functional group, initial columbic efficiency
  • 出版物名称:   INTERNATIONAL JOURNAL OF ELECTROCHEMICAL SCIENCE
  • ISSN:   1452-3981
  • 通讯作者地址:   Chinese Acad Sci
  • 被引频次:   2
  • DOI:   10.20964/2019.01.75
  • 出版年:   2019

▎ 摘  要

For lithium-ion batteries (LIBs), poor initial coulombic efficiency and poor cyclic performance of graphene oxide (GO) are facing great challenge in commercial application. This paper describes a class of active composites consisting of reduced graphene oxide (rGO) and graphite used as promising LIBs anodes. In addition to adjust the functional groups to decrease the irreversible capacity effectively, the construction of a conductive network between rGO and graphite synthesized during an ultrasonic process shortened the lithium ion migration path. The residual stable functional groups after thermal treatment also enhance the cyclic performance of the electrodes. Electrochemical test results revealed a high reversible Li-storage capacity of 446 mAh g(-1) at 0.1 C (1 C=372 mAh g(-1)), improved initial coulombic efficiency of 84.2% and superior cyclic performance with capacity retention of 93.8% after more than 400 cycles, showing great potential of this rGO/graphite anode material.