• 文献标题:   A Facile Fabrication of Fe3O4/Graphene Nanosheets for Lithium-Ion Battery
  • 文献类型:   Article
  • 作  者:   LI Y, ZHU SM, YU ZY, MENG Q, ZHANG T, LIU QL, GU JJ, ZHANG W, LU T, ZHU CL, GUO ZP, MA J, ZHANG D
  • 作者关键词:   hydrothermal method, fe3o4 nanoparticle, graphene nanosheet, lithium ion battery
  • 出版物名称:   SCIENCE OF ADVANCED MATERIALS
  • ISSN:   1947-2935 EI 1947-2943
  • 通讯作者地址:   Shanghai Jiao Tong Univ
  • 被引频次:   12
  • DOI:   10.1166/sam.2014.1713
  • 出版年:   2014

▎ 摘  要

In this study, Fe3O4/graphene nanosheets (Fe3O4/GNSs) nanocomposite was synthesized by using the combination of simple hydrothermal treatment and calcination. It was found Fe3O4 nanoparticles with diameter of 15 nm were synthesized and uniformly dispersed on the surface of graphene nanosheets (GNSs). When our cost-effective Fe3O4/GNSs was employed as an anode material in lithium-ion battery, it exhibited a high reversible capacity of 740 mA h/g after 100 cycles at a current density of 100 mA/g. This high performance is attributed to the following reasons: (i) the nanoparticles down to similar to 15 nm act not only as electrochemical active sites but as spacers, (ii) GNSs that carry the nanoparticles enhance electron transport by providing conductive pathways, and (iii) Fe3O4/GNSs creates a three-dimensional architecture that effectively facilitates ion diffusion and lithium-ion storage. This finding would open up an efficient route for synthesis and application of GNSs hybrids as anode materials for lithium-ion batteries of high performance.