• 文献标题:   Magnetite graphene oxide modified with beta-cyclodextrin as an effective adsorbent for the removal of methotrexate and doxorubicin hydrochloride from water
  • 文献类型:   Article
  • 作  者:   GHAFOORI M, CHERAGHI M, SADR MK, LORESTANI B, SOBHANARDAKANI S
  • 作者关键词:   adsorption, aqueous solution, go@fe3o4@betacd, isotherm, pharmaceutical compound
  • 出版物名称:   ENVIRONMENTAL SCIENCE POLLUTION RESEARCH
  • ISSN:   0944-1344 EI 1614-7499
  • 通讯作者地址:  
  • 被引频次:   10
  • DOI:   10.1007/s11356-022-18725-x EA JAN 2022
  • 出版年:   2022

▎ 摘  要

The purpose of this investigation was to analyze the performance of magnetite graphene oxide modified with beta-cyclodextrin (GO@Fe3O4@beta-CD) for adsorption of methotrexate (MTX) and doxorubicin (DOX) from aqueous solutions. Characterization of GO@Fe3O4@beta-CD was carried out using some methods. The perfect conditions for the adsorption of MTX and DOX were 7.0, 45 min, 20 mg, and 25 degrees C for solution pH, contact time, adsorbent dose, and temperature, respectively, with removal efficiency values of 97.8% and 98.5% for MTX and DOX, respectively. The adsorption kinetic of MTX and DOX via GO@Fe3O4@beta-CD followed pseudo second-order (PSO) model, while the adsorption isotherm obeyed Langmuir model by monolayer adsorption with maximum adsorption capacities of 198.5 and 204.5 mg g(-1) for MTX and DOX, respectively. Therefore, it could be argued that HCl and 0.1 mol L-1 NaOH would reflect adequate elution properties for GO@Fe3O4@beta-CD recovery.