• 文献标题:   Scalable Fabrication of Si-Graphene Composite as Anode for Li-ion Batteries
  • 文献类型:   Article
  • 作  者:   LOU D, CHEN SY, LANGRUD S, RAZZAQ AA, MAO MY, YOUNES H, XING WB, LIN T, HONG HP
  • 作者关键词:   sigraphene electrode, liion batterie, anode, scalable
  • 出版物名称:   APPLIED SCIENCESBASEL
  • ISSN:  
  • 通讯作者地址:  
  • 被引频次:   2
  • DOI:   10.3390/app122110926
  • 出版年:   2022

▎ 摘  要

A facile and scalable method is reported to fabricate Si-graphene nanocomposite as anode material for Li-ion batteries (LIBs) with high capacity and capacity retention performance. The Si-graphene electrode showed an initial discharge capacity of 1307 mAh g(-1) at a current rate of 0.1C. At the 25th cycle, the electrode retained a discharge capacity of 1270 mAh g(-1), with an excellent capacity retention of 97%. At the 50th cycle, the electrode still retained high capacity retention of 89%. The improved capacity retention of Si-graphene anode compared with Si anode is attributed to the mechanical flexibility of graphene that compromises the volume expansion of Si during the lithiation/delithiation process. The electrochemical impedance measurement further confirms the enhanced electrical conductivity and the denser solid-electrolyte-interface of the Si-graphene electrode. This fabrication approach is cost-effective and easy to scale up compared to known techniques, making it a promising candidate for commercializing Si-based anode for LIBs.