• 文献标题:   Supercapacitor electrodes with especially high rate capability and cyclability based on a novel Pt nanosphere and cysteine-generated graphene
  • 文献类型:   Article
  • 作  者:   ZHANG DC, ZHANG X, CHEN Y, WANG CH, MA YW, DONG HL, JIANG L, MENG Q, HU WP
  • 作者关键词:  
  • 出版物名称:   PHYSICAL CHEMISTRY CHEMICAL PHYSICS
  • ISSN:   1463-9076 EI 1463-9084
  • 通讯作者地址:   Chinese Acad Sci
  • 被引频次:   14
  • DOI:   10.1039/c2cp41051f
  • 出版年:   2012

▎ 摘  要

In the present work, supercapacitors based on graphene/Pt films show especially high rate capability (120 F g(-1) even at 50 A g(-1)) and cyclability (no attenuation over 10 000 cycles) and peculiar nanosphere morphology after electrochemical cycling. Furthermore, supercapacitors based on the graphene powder with a binder exhibit high specific capacitance (249 F g(-1) at 0.1 A g(-1)), long cycle life (no attenuation over 40 000 cycles) and high rate capability (150 F g(-1) even at 50 A g(-1)), which are much better than those of most graphene electrode materials. These indicate the great potential of the cysteine reduced graphene electrodes in energy storage.