• 文献标题:   An impedimetric e-tongue based on CeO2-graphene oxide chemical sensors for detection of glyphosate and its potential interferents
  • 文献类型:   Article
  • 作  者:   COSTA IA, GROSS MA, ALVES EDO, FONSECA FJ, PATERNO LG
  • 作者关键词:   herbicide, glyphosate paradox, sensor array, ceo2 nanoparticle, impedance spectroscopy
  • 出版物名称:   JOURNAL OF ELECTROANALYTICAL CHEMISTRY
  • ISSN:   1572-6657 EI 1873-2569
  • 通讯作者地址:  
  • 被引频次:   1
  • DOI:   10.1016/j.jelechem.2022.116719 EA AUG 2022
  • 出版年:   2022

▎ 摘  要

Glyphosate (GLY) is the most common and widespread herbicide applied to prevent unwanted weeds. However, its detection with conventional analytical methods is a hard task. In this regard, this contribution proposes an original impedimetric electronic tongue (IET) based upon CeO2-graphene oxide chemical sensors and principal component analysis for easier detection of GLY. This IET was capable of detecting GLY within a linear range of concentrations, 110 to 290 nmol/L (R-2 = 0.99), showing a limit of detection of 30 nmol/L, which is far below that established by international safety regulations. This was made possible even in the presence of potential interferents, namely aminomethyl phosphonic acid and N-nitroso glyphosate. The IET per-formed identically to quantitative 1H NMR at 95 % confident level. Once it does not rely on redox reactions or previous derivatization, this IET is a simpler alternative to detect and monitor GLY and its interferents in aqueous media.