• 文献标题:   Ethanol electrooxidation on highly active palladium/graphene oxide aerogel catalysts
  • 文献类型:   Article
  • 作  者:   ZHANG J, ZHAO ZL, WANG YZ, WANG J, PENG DC, LI BY, BO TT, ZHENG K, ZHOU ZY, LV L, XIN ZL, ZHANG BS, SHAO LD
  • 作者关键词:   pd nanoparticle, ethanol oxidation reaction, graphene oxide, aerogel, functional group
  • 出版物名称:   CHEMICAL PHYSICS
  • ISSN:   0301-0104 EI 1873-4421
  • 通讯作者地址:   Shanghai Univ Elect Power
  • 被引频次:   2
  • DOI:   10.1016/j.chemphys.2020.110753
  • 出版年:   2020

▎ 摘  要

In this work, the low-loading (3 wt%) palladium/graphene oxide (Pd/GO) aerogels are facilely prepared via the lyophilisation, vacuum and reduction treatments. The Pd/GO aerogels display enhanced activity and stability in comparison to the commercial Pd/C. The enhancement of electrocatalytic performance can be attributed to the functional groups on the surfaces of the GO support, such as carbonyl and carboxyl groups, which can be tuned to interact with palladium to form active phases for the reaction. In addition, Pd nanoparticles (NPs) remain dispersed in nanoscale on the reacted catalyst.