• 文献标题:   Green starch/graphene oxide hydrogel nanocomposites for sustained release applications
  • 文献类型:   Article
  • 作  者:   SAYED A, YASSER M, ABDELRAOUF MES, MOHSEN R
  • 作者关键词:   biopolymer, gammairradiation, polymerization, characterization, atomic force microscopy, swelling study
  • 出版物名称:   CHEMICAL PAPERS
  • ISSN:   0366-6352 EI 2585-7290
  • 通讯作者地址:  
  • 被引频次:   10
  • DOI:   10.1007/s11696-022-02236-7 EA MAY 2022
  • 出版年:   2022

▎ 摘  要

Green nanocomposite hydrogels (ST-PHEMA/GO) comprised of starch and 2-Hydroxyethyl methacrylate (HEMA) reinforced with different ratios of graphene oxide (GO) were prepared via gamma radiation induced crosslinking polymerization. The chemical structure and morphology and the crystallinity were studied by FTIR FE-SEM, AFM, TEM and XRD, respectively. The swelling behavior of the claimed hydrogels was verified versus time and the pH-dependent swelling at three different irradiation dose:10, 20 and 30 kGy was also investigated. The results of the swelling study showed that the swelling capacity of the hydrogel networks varied with the changes of the pH of the solution, the GO content and the irradiation doses. Moreover, the swelling isotherm of all the prepared hydrogels followed a Fickian diffusion mechanism n < 0.5. [GRAPHICS]