• 文献标题:   Growing vertical graphene sheets on natural graphite for fast charging lithium-ion batteries
  • 文献类型:   Article
  • 作  者:   MU YB, HAN MS, LI JY, LIANG JB, YU J
  • 作者关键词:   fast charging, high energy density, battery, anode, graphene
  • 出版物名称:   CARBON
  • ISSN:   0008-6223 EI 1873-3891
  • 通讯作者地址:  
  • 被引频次:   41
  • DOI:   10.1016/j.carbon.2020.11.027
  • 出版年:   2021

▎ 摘  要

A goal of extreme fast charging less than 15 min recharge time while maintaining high energy density has been pursued to meet fast-charging and high-energy-density demand on lithium ion batteries used in electric vehicles, which is still a challenge. Here, in order to realize the goal vertical graphene sheets are grown on surface of graphite by thermal chemical vapor deposition. The vertical graphene sheets not only can greatly boost lithium-ion transport rate due to its intrinsically high electrical conductivity but also can significantly reduce tortuosity of lithium ion transport due to its highly preferential lithium-ion insertion paths. In half cells, the vertical graphene sheets/graphite can endure 3000 cycles in 3 min of charge time per cycle. More remarkably, a full cell with vertical graphene sheets/graphite anode and LiFePO4 cathode exhibits an ultrahigh energy density of 312.1 Wh kg(-1) in 10 min of charge time per cycle at 4 C, indicating that the vertical graphene sheets/graphite anode possesses ability of extreme fast charging while maintaining high energy density. (C) 2020 Elsevier Ltd. All rights reserved.