• 文献标题:   Electrically tunable SERS based on plasmonic gold nanorod-graphene/ion-gel hybrid structure with a low voltage
  • 文献类型:   Article
  • 作  者:   ZHOU L, CHEN XY, REN GH, CHEN LG, XU WW, GU CJ, ZHANG WT, LI YF, TIAN Z, ZHOU J, HAN JG
  • 作者关键词:   surfaceenhanced raman scattering, graphene, iongel, electrostatic doping, fermi level, charge transfer
  • 出版物名称:   CARBON
  • ISSN:   0008-6223 EI 1873-3891
  • 通讯作者地址:  
  • 被引频次:   2
  • DOI:   10.1016/j.carbon.2021.11.040
  • 出版年:   2022

▎ 摘  要

Actively controlling the performance of surface-enhanced Raman scattering (SERS) holds great promise in enabling novel applications of this technique. As a popular two-dimensional material, graphene shows intriguing tunable properties and thus has become a promising material in many potential active device applications. Here we proposed and experimentally demonstrated low-voltage electrically tunable SERS by using a plasmonic gold nanorod-graphene/ion-gel hybrid structure. The SERS signals of molecules adsorbed on such a structure were found to be continuously tunable through an external small bias voltage. As such a tuning process is highly related with the charge transfer between the adsorbed molecules and graphene, the proposed design is also helpful in understanding the charge transfer-based enhancement mechanism of SERS. (C) 2021 Elsevier Ltd. All rights reserved.