• 文献标题:   Paper-based electrochemical sensors with reduced graphene nanoribbons for simultaneous detection of sulfamethoxazole and trimethoprim in water samples
  • 文献类型:   Article
  • 作  者:   MARTINS TS, BOTTNETO JL, OLIVEIRA ON, MACHADO SAS
  • 作者关键词:   fully printed sensor, reduced graphene nanoribbon, simultaneous determination, antibiotic, water supply monitoring
  • 出版物名称:   JOURNAL OF ELECTROANALYTICAL CHEMISTRY
  • ISSN:   1572-6657 EI 1873-2569
  • 通讯作者地址:  
  • 被引频次:   32
  • DOI:   10.1016/j.jelechem.2021.114985 EA JAN 2021
  • 出版年:   2021

▎ 摘  要

Failure to control the levels of emerging pollutants in water supply can affect the quality of human life, and this maybe mitigated with a low-cost, real-time monitoring system. Herein, we describe a paper-based fully printed electrochemical sensor with reduced graphene nanoribbons (rGNR) capable of detecting sulfamethoxazole (SMX) and trimethoprim (TMP) antibiotics simultaneously in real water samples. The electrodes were printed on parchment paper, which is environmentally friendly and has an efficient printing capacity. Deposition of rGNRs in the matrix was confirmed with Raman spectroscopy, transmission electron microscopy (TEM), and X-ray photoemission spectroscopy (XPS). Optimized sensing performance was obtained using an electrochemical treatment of the electrodes at neutral pH. The paper-based sensor displayed a linear response from 1 mu mol l-1 to 10 mu mol l-1 for both antibiotics, with detection limits of 0.09 mu mol l-1 and 0.04 mu mol l-1 for SMX and TMP, respectively. The sensor was reproducible, with an RSD below 5%,and selective for the antibiotics including in real samples, in a demonstration of its potential for realtime monitoring of water supply systems.