• 文献标题:   Biochar-supported carbon nanotube and graphene oxide nanocomposites for Pb(II) and Cd(II) removal
  • 文献类型:   Article
  • 作  者:   LIU TZ, GAO B, FANG JN, WANG B, CAO XD
  • 作者关键词:  
  • 出版物名称:   RSC ADVANCES
  • ISSN:   2046-2069
  • 通讯作者地址:   Univ Florida
  • 被引频次:   24
  • DOI:   10.1039/c6ra01895e
  • 出版年:   2016

▎ 摘  要

Carbon materials such as nanoparticles have provided new solutions for the removal of various environmental contaminants. In this work, two carbon nanomaterial-biochar nanocomposites (SG-PySA-CNT and SG-PySA-GO) were derived from sweetgum biomass pretreated with carbon nanotubes (CNTs) and graphene oxide (GO) through slow pyrolysis at 600 degrees C. Both SG-PySA-CNT and SG-PySA-GO had higher surface area but much lower pore volume than the pristine biochar (SG). Batch sorption experimental results showed that SG-PySA-CNT and SG-PySA-GO had greater sorption ability to Pb(II) and Cd(II) from aqueous solution than SG. SG-PySA-GO was the best sorbent with maximum sorption capacities higher than 40 and 10 mg g(-1) for Pb(II) and Cd(II), respectively. The enhanced metal sorption by the biochar nanocomposites could be mainly attributed to the excellent sorptive properties of the carbon nanoparticles (CNT/GO) distributed and stabilized on the biochar surfaces within the matrix. Because of its facile synthesis and good sorptive properties, biochar-supported CNT and GO nanocomposites have great potential to be used in various environmental applications for the removal of metal and metalloid contaminants.