• 文献标题:   Synthesis of fluorescent graphene quantum dots from graphene oxide and their application in fabrication of GQDs@AgNPs nanohybrids and sensing of H2O2
  • 文献类型:   Article
  • 作  者:   MEHATA MS, BISWAS S
  • 作者关键词:   go nanosheet, gqd, gqds@agnps nanohybrid, chemical synthesi, absorption photoluminescence, h2o2 sensor
  • 出版物名称:   CERAMICS INTERNATIONAL
  • ISSN:   0272-8842 EI 1873-3956
  • 通讯作者地址:  
  • 被引频次:   8
  • DOI:   10.1016/j.ceramint.2021.03.252 EA MAY 2021
  • 出版年:   2021

▎ 摘  要

Graphene oxide (GO) with hydrophilic properties supports the scalable production of highly desirable material graphene. GO nanosheets were prepared with a modified Hummers method, whereas the oxidative cutting technique was used to synthesize graphene quantum dots (GQDs). The surface and structural morphology of both GO and GQDs were examined and compared. In GO, photoluminescence originated mainly due to the conductive electrons present in the sp(2) localized sites and the excimer formation. In contrast, in GQDs, PL is increased due to numerous defects present on their surfaces. The pH plays a crucial role in tuning the blue and green PL of GQDs hence the optical properties. The developed GQDs with functional groups act as a solo reducing and stabilizing agent in producing the GQDs-silver nanoparticles (GQDs@AgNPs) hybrid structure, which exhibits strong surface plasmon resonance along with GQDs absorption. Further, GQDs alone support sensing of hydrogen peroxide (H2O2) in an aqueous medium, thus acting as a sensing probe like the GQDs@AgNPs nanohybrids.