• 文献标题:   Decomposition of Formic Acid on Pt/N-Graphene
  • 文献类型:   Article
  • 作  者:   CHESNOKOV VV, LISITSYN AS, SOBOLEV VI, GERASIMOV EY, PROSVIRIN IP, CHESALOV YA, CHICHKAN AS, PODYACHEVA OY
  • 作者关键词:   platinum, graphene, nitrogen, hydrogen, formic acid
  • 出版物名称:   KINETICS CATALYSIS
  • ISSN:   0023-1584 EI 1608-3210
  • 通讯作者地址:  
  • 被引频次:   2
  • DOI:   10.1134/S0023158421040017
  • 出版年:   2021

▎ 摘  要

The properties of a new catalytic Pt/N-graphene system in the gas-phase reaction of formic acid decomposition for the production of pure hydrogen were studied. Graphene powders undoped and doped with nitrogen atoms were used as carbon supports. Raman spectroscopy, X-ray photoelectron spectroscopy (XPS), high-resolution transmission electron microscopy (TEM), and the chemisorption of CO were used to characterize the synthesized catalysts. It was found that the activity of the catalysts increased upon graphene doping with nitrogen atoms and with increasing the platinum concentration from 0.2 to 1 wt %; the catalyst selectivity in the test reaction was as high as 96-99%.