• 文献标题:   In situ synthesis of TiO2-graphene nanosheets composites as anode materials for high-power lithium ion batteries
  • 文献类型:   Article
  • 作  者:   TAO HC, FAN LZ, YAN XQ, QU XH
  • 作者关键词:   graphene, titanium dioxide, anode, lithium ion batterie, nanocomposite
  • 出版物名称:   ELECTROCHIMICA ACTA
  • ISSN:   0013-4686 EI 1873-3859
  • 通讯作者地址:   Beijing Univ Sci Technol
  • 被引频次:   52
  • DOI:   10.1016/j.electacta.2012.03.022
  • 出版年:   2012

▎ 摘  要

TiO2-graphene nanosheets (GNS) composites are prepared via an in situ chemical synthesis method, which enables a homogenous dispersion of TiO2 nanoparticles on the graphene nanosheets. The obtained TiO2-GNS composites are anatase-GNS, while TiO2 is nanosized rutile without the incorporation of GNS. The resulting TiO2-GNS composites are employed as anode materials for lithium-ion batteries, showing a high initial reversible capacity of 306 mAh g(-1) as well as a good cycling stability. The TiO2-GNS composites can deliver 60 mAh g(-1) at a current rate as high as 5 A g(-1) and demonstrate negligible fade even after 400 cycles. The superior electrochemical performances of the TiO2-GNS composites can be attributed to their unique structures, which intimately combine the conductive graphene nanosheets network with uniformly dispersed TiO2 nanoparticles. The TiO2-GNS composites could be promising candidate materials for high-power, low-cost, and environmentally friendly anodes for lithium ion batteries. (C) 2012 Elsevier Ltd. All rights reserved.