• 文献标题:   Ionic liquid modified graphene aerogel as efficient electrode material for supercapacitors based on ionic liquid electrolyte
  • 文献类型:   Article
  • 作  者:   LI H, HU XD, WANG CF, CHEN YJ, ZHUO KL, WANG JJ
  • 作者关键词:   hydrothermal reaction, ionic liquid modification, graphene aerogel, porous texture, energy density, symmetric supercapacitor
  • 出版物名称:   INTERNATIONAL JOURNAL OF HYDROGEN ENERGY
  • ISSN:   0360-3199 EI 1879-3487
  • 通讯作者地址:  
  • 被引频次:   0
  • DOI:   10.1016/j.ijhydene.2022.04.1110360-3199
  • 出版年:   2022

▎ 摘  要

The simultaneous enhancement of energy density (E) and power density (P) is a highly pursued but difficult task in domain of supercapacitors, which necessitates good electrode/ electrolyte compatibility, high electron/ion migration rates, and wide voltage window. Herein, an ionic liquid (IL) assisted hydrothermal reduction and modification tactics is employed to prepare 1-benzyl-3-methyl imidazolium cysteine ([Bzmim][Cys]) IL-modified reduced graphene oxide aerogel material (IL-rGA). The porous texture with suitable pore sizes and IL-modified surface of IL-rGA ensures rapid infiltration and sufficient adsorption of electrolyte ions, and therefore substantially enhances the specific capacitance. The symmetric IL-rGA supercapacitor using 1-ethyl-3-methyl tetrafluoroborate IL electrolyte delivers high E values of 104-33 W h kg-1 in the P range of 944-15,860 W kg-1, these output parameters can meet the requirements in more widespread electric facilities. The current work offers a promising way to enhance and balance the E and P values of carbonaceous supercapacitors via the surface modification of electrode materials and the matching with IL electrolytes.(c) 2022 Hydrogen Energy Publications LLC. Published by Elsevier Ltd. All rights reserved.