▎ 摘　　要

The dendrite growth and irreversibility of lithium (Li) metal anode seriously hinders the wide-scale application of high-energy-density rechargeable batteries. Here, we report a thin Janus-faced graphene substrate, consisting of lithiophilic-lithiophobic faces separately, for Li plating/stripping. The visualized analysis demonstrates that the unique Janus-faced graphene structure provides different lithiophilic sites and pore channels to steer the Li electrodeposition and suppress the dendrite growth. As expected, the Janus-faced graphene anode achieves longterm Li plating/stripping with high Coulombic efficiency, small polarization and stable cycling throughout the symmetry, asymmetry and LiFePO4 full cells. Such an encouraging strategy for reversible Li plating/stripping provides a promising way to design long-life carbon-base anode materials for Li metal batteries.