• 文献标题:   Low Vacuum Annealing of Cellulose Acetate on Nickel Towards Transparent Conductive CNT-Graphene Hybrid Films
  • 文献类型:   Article
  • 作  者:   NGUYEN DD, TIWARI RN, MATSUOKA Y, HASHIMOTO G, ROKUTA E, CHEN YZ, CHUEH YL, YOSHIMURA M
  • 作者关键词:   graphene, carbon nanotube, transparent conducting film, surface precipitation, low vacuum annealing, cntgraphene hybrid film
  • 出版物名称:   ACS APPLIED MATERIALS INTERFACES
  • ISSN:   1944-8244
  • 通讯作者地址:   Toyota Technol Inst
  • 被引频次:   19
  • DOI:   10.1021/am5003469
  • 出版年:   2014

▎ 摘  要

We report a versatile method based on low vacuum annealing of cellulose acetate on nickel (Ni) surface for rapid fabrication of graphene and carbon nanotube (CNT)-graphene hybrid films with tunable properties. Uniform films mainly composed of tri-layer graphene can be achieved via a surface precipitation of dissociated carbon at 800 degrees C for 30 seconds under vacuum conditions of similar to 0.6 Pa. The surface precipitation process is further found to be efficient for joining the precipitated graphene with pre-coated CNTs on the Ni surface, consequently, generating the hybrid films. As expected, the hybrid films exhibit substantial opto-electrical and field electron emission properties superior to their individual counterparts. The finding suggests a promising route to hybridize the graphene with diverse nanomaterials for constructing novel hybrid materials with improved performances.