• 文献标题:   Amino-Fe3O4-functionalized multi-layered graphene oxide as an ecofriendly and highly effective nanoscavenger of the reactive drimaren
  • 文献类型:   Article
  • 作  者:   FRAGA TJM, DA SILVA LFF, FERREIRA LEMD, DA SILVA MP, FRAGA DMDM, DE.ARAUJO CMB, CARVALHOL MN, CAVALCANTI JVFD, GHISLANDI MG, SOBRINHO MAD
  • 作者关键词:   multilayer graphene oxide, functionalization, adsorption, drimaren red, phytotoxicity, textile wastewater
  • 出版物名称:   ENVIRONMENTAL SCIENCE POLLUTION RESEARCH
  • ISSN:   0944-1344 EI 1614-7499
  • 通讯作者地址:   Univ Fed Pernambuco UFPE
  • 被引频次:   3
  • DOI:   10.1007/s11356-019-07539-z
  • 出版年:   2020

▎ 摘  要

Amino-functionalized multilayer graphene oxide (Am-nGO) has been synthesized and applied to remove the reactive drimaren red (DR) from aqueous solutions. Infrared spectroscopy evidenced amine and amide presence by peaks at 1579 cm(-1) and a band between 3300 and 3500 cm(-1). Raman spectroscopy showed an increment in I-D/I-G ratio after amino-Fe3O4-functionalization of nGO from 1.05 to 1.20, referent to an increase in sp(3) domain disorder. The isoelectric point of Am-nGO was pH 8.1. From kinetic study, the equilibrium was achieved within 90 min; moreover, pseudo-n-order model satisfactorily fitted to the experimental data. Kinetic constant (k(n)) was 0.71 mg(1-n) g(1-n) min(-1) and modeled equilibrium sorption capacity (q(e)) 219.17 mg g(-1). Equilibrium experiments showed monolayer adsorption capacity (q(m)) of 219.75 mg g(-1), and BET model best fitted to the equilibrium data, indicating that the adsorption process happened with multiple layers formation. From sorption thermodynamics, the standard free energy of Gibbs and enthalpy were respectively - 31.91 kJ mol(-1) (at 298 K) and 66.43 kJ mol(-1). Such data evidence the spontaneous and chemical behavior of DR adsorption as a consequence of strong electron donor-receptor interactions between the dye and the nanosorbent. By phytotoxicity assessment, Am-nGO showed inexpressive inhibitory potential to American lettuce seeds in comparison with its precursor nGO and graphite nanoplatelets.