▎ 摘　　要

There are ever increasing interests in three dimensional (3D) graphene for the construction of wearable electrics and flexible energy storage devices. Herein, we report a 3D porous graphene supported poly aniline (PANI) nanoarrays composite with enhanced interface bonding and high load fraction of PANI for supercapacitor application. We demonstrate that by utilizing benzenesulfonic acid functionalization followed by a pre-immersion treatment, surface chemistry and permeability of the porous graphene can be improved significantly, which favors the controllable growth of high-quality PANI nanoarrays. The resulting composite used as a freestanding electrode exhibits excellent electrochemical performance, hence a maximum specific capacitance of 752 F/g with retention of 90.8% over 10000 cycles was achieved. (C) 2017 Elsevier Ltd. All rights reserved.