• 文献标题:   Selective and sensitive determination of dopamine by composites of polypyrrole and graphene modified electrodes
  • 文献类型:   Article
  • 作  者:   SI P, CHEN HL, KANNAN P, KIM DH
  • 作者关键词:  
  • 出版物名称:   ANALYST
  • ISSN:   0003-2654
  • 通讯作者地址:   Nanyang Technol Univ
  • 被引频次:   83
  • DOI:   10.1039/c1an15772h
  • 出版年:   2011

▎ 摘  要

A novel method is developed to fabricate the polypyrrole (PPy) and graphene thin films on electrodes by electrochemical polymerization of pyrrole with graphene oxide (GO) as a dopant, followed by electrochemical reduction of GO in the composite film. The composite of PPy and electrochemically reduced graphene oxide (eRGO)-modified electrode is highly sensitive and selective toward the detection of dopamine (DA) in the presence of high concentrations of ascorbic acid (AA) and uric acid (UA). The sensing performance of the PPy/eRGO-modified electrode is investigated by differential pulse voltammetry (DPV), revealing a linear range of 0.1-150 mu M with a detection limit of 23 nM (S/N = 3). The practical application of the PPy/eRGO-modified electrode is successfully demonstrated for DA determination in human blood serum.