• 文献标题:   Oxidation of graphene-modified HfB2-SiC ceramics by supersonic dissociated air flow
  • 文献类型:   Article
  • 作  者:   SIMONENKO EP, SIMONENKO NP, KOLESNIKOV AF, CHAPLYGIN AV, LYSENKOV AS, NAGORNOV IA, SIMONENKO TL, GUBIN SP, SEVASTYANOV VG, KUZNETSOV NT
  • 作者关键词:   ceramic, graphene, uhtc, solgel processe, induction plasmatron
  • 出版物名称:   JOURNAL OF THE EUROPEAN CERAMIC SOCIETY
  • ISSN:   0955-2219 EI 1873-619X
  • 通讯作者地址:  
  • 被引频次:   7
  • DOI:   10.1016/j.jeurceramsoc.2021.09.020 EA OCT 2021
  • 出版年:   2022

▎ 摘  要

The oxidation resistance of ultra-high-temperature ceramic material (HfB2-30 vol%SiC)-2 vol%rGO (rGO: reduced graphene oxide) under long-term exposure (2000s) to a supersonic air flow has been studied. The ceramics were obtained by reactive hot pressing of HfB2-(SiO2-C)-rGO composite powder at a temperature of 1800 degrees C (pressure 30 MPa, holding time 15 min, Ar). The surface temperature of graphene-modified ceramics under the influence of heating by high-enthalpy air flow (heat flow q reached 779 W.cm(-2)) did not exceed 1700 degrees C, which is 650-700 degrees C less than for the HfB2-30 vol%SiC baseline ceramics. This may be related to an increase in the efficiency of heat transfer from the sample to the water-cooled module, due to the higher thermal conductivity of the rGO-containing material. Thereby, a decrease in the material degradation degree has been noted, i.e. decrease in the recession rate and decrease in the total thickness of the oxidised ceramic layer by tenth. The peculiarities of the oxidised surface and near-surface region microstructure upon aerodynamic heating of the graphene-modified ceramic material, have been shown.